منابع مشابه
Total syntheses of echinopines.
A concise and scalable synthesis of a cis-fused bicyclo[5.3.0]decane ring system has been developed for the total synthesis of echinopines. The core of the natural products was constructed efficiently through an intramolecular 1,3-dipolar cycloaddition and ring contraction strategy.
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A function f defined on the vertices of a graph G = (V ,E), f : V → {−1, 0, 1} is a total minus dominating function (TMDF) if the sum of its values over any open neighborhood is at least one. The weight of a TMDF is the sum of its function values over all vertices. The total minus domination number, denoted by −t (G), of G is the minimum weight of a TMDF on G. In this paper, a sharp lower bound...
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A convergent, stereocontrolled route to either antipode of the cell adhesion inhibitor, peribysin E, has been achieved from carvone. Highlights of the synthesis include a Diels-Alder reaction to generate a cis-decalin framework, followed by semipinacol-type ring contraction to secure the stereochemistry of the C7 quaternary center. Potential mechanistic pathways for the critical ring contractio...
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The first total syntheses of (+)- and (-)-subereamollines A and B are reported. The enantiomeric forms of the natural products were obtained by preparative chiral HPLC separation of the corresponding racemates.
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ژورنال
عنوان ژورنال: Journal of Synthetic Organic Chemistry, Japan
سال: 2014
ISSN: 0037-9980,1883-6526
DOI: 10.5059/yukigoseikyokaishi.72.72